The functionality to use a background image while rending used to be available in earlier versions of Revit. The new Mental Ray rendering engine includes the ability to create a generated sky and sun but if you need to show a specific background or site the ability to add an image is no longer available.
There is an alternative that you can use to get a background image in your rendering.
You can export the Rendering to a TIFF format which exports the sky as a separate alpha channel. This makes replacing the sky in an image editor much easier. You can use Photoshop or any other image editors that read and write the TIFF file format. However, this can be a little bit extra work and requires another program.
There is a way to get around this problem and do this all inside of Revit.